Effective removal of organic pollution by using sonochemical prepared LaFeO₃ perovskite under visible light

In the present work, LaFeO₃ perovskite was prepared via ultrasonic probe with power of 60 W and frequency of 18 KHz. LaFeO₃ nanorods were formed when sonication time was 20 min. In this research, green materials including corn, starch, and rice were used to control the size, morphology, and purity of final products. As-prepared LaFeO₃ nanostructures were used to purify water containing organic contaminants. LaFeO₃ nanostructures prepared by using corn, starch, and rice showed higher photocatalytic activity compare to LaFeO₃ nanostructures without natural capping agents. Using corn increased degradation efficiency by 65% under visible light. XRD results show that Fe₂O₃ appeared as an impurity when starch was used to prepare LaFeO₃ nanostructures. This impurity significantly boosts the degradation efficiency under UV light. Fe₂O₃ under UV light act as co-absorbent and boost efficiency by 43%. LaFeO₃ nanostructures were characterized by XRD, EDX, SEM, CV, BET, TEM, DRS and FT-IR.