Amperometric sensing of catechol by using a nanocomposite prepared from Ag/Ag2O nanoparticles and N,S-doped carbon...

This work describes the synthesis of a nanocomposite consisting of Ag₂O, silver nanoparticles and N,S-doped carbon quantum dots (Ag₂O/Ag@NS-CQD). The NS-CQD were prepared by hydrothermal treatment of p-aminobenzenesulfonic acid. They act as both the reducing and stabilizing agent for synthesis of Ag₂O/Ag@NS-CQD. The composite was characterized by UV-vis spectroscopy, transmission electron microscopy, X-ray diffraction and X-ray photoelectron spectroscopy. The glassy carbon electrode (GCE) was modified by coating it with Ag₂O/Ag@NS-CQD. It exhibits excellent amperometric response to catechol, typically at a low working potential of around 0.25 V. Under the best experimental conditions, the sensor has a wide linear response (0.2 to 180 μM) and a low detection limit (13 nM; at S/N = 3). The method was applied to analysis of spiked water samples and gave satisfactory results. Graphical abstract Schematic representation of the preparation of the Ag/Ag2O@N,S-doped carbon quantum dots composite using p-aminobenzenesulfonic acid and silver nitrate as the starting materials. The corresponding modified glassy carbon electrode exhibits the excellent amperometric sensing performance toward catechol at pH 7.0 with low detection limit and good selectivity.