Decomposition of n-hexane using a dielectric barrier discharge plasma

In this study, we investigated the decomposition characteristics of n-hexane by a dielectric barrier discharge (DBD) plasma. In order to accomplish this, the factors influencing these decomposition characteristics such as background gases (air, N₂, and He), residence time (1-10 s), initial n-hexane concentration (10-50 ppm), relative humidity (2.5%, 40%, and 70%), and power (50-80 W) were evaluated. As a result, the decomposition efficiency of n-hexane at N₂ atmosphere was found to be lower than those at air and He atmosphere. The removal efficiency of n-hexane was increased when the residence time, relative humidity, and power increased, and when the initial concentration decreased. The concentrations of CO, CO₂, and aerosol increased as the specific energy density increased. However, the O₃ level increased up to a certain point, then decreased. Various hydrocarbons such as acetone, pentanal, nonanal, etc. were also detected as by-products and their decomposition and recombination pathways were suggested.