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Updated: Jan 4, 2026

Atom Transfer Radical Polymerization of Functionalized Vinyl Monomers Using Perylene as a Visible Light Photocatalyst
Published on: April 22, 2016
Synthesis of PAN with adjustable molecular weight and low polydispersity index (PDI) value via reverse atom transfer
Shuang Li1, Yazhen Wang2, Liqun Ma1
1College of Materials Science and Engineering, Qiqihar University, Qiqihar, China.
Abstract:
The reverse atom transfer radical polymerization (RATRP) of acrylonitrile (AN) was carried out in N, N-dimethylformamide (DMF) with AIBN as initiator, FeCl3•6H2O/triphenylphosphine (PPh3) and FeCl3•6H2O/pentamethyldle-thylenetrlamlne (PMDETA) as catalytic systems, respectively. Effect of reaction time and initiator concentration on polymerization rate, molecular weight and molecular weight distribution were investigated in detail. The Fourier transform infrared spectrometer (FTIR) and 1H nuclear magnetic resonance spectroscopy (1HNMR) were employed to analyze the chain end of the PAN. Gel permeation chromatography (GPC) was applied to measure the molecular weight and polydispersity index (PDI) of PAN. The polymerization demonstrated a typical pseudo first-order kinetics characteristics as evidenced by the number-average molecular weights (Mn) increasing linearly with monomer conversion; the Mn decreasing with the increasing of the initiator concentration. Meanwhile, the low PDI value (<1.2) indicated the controllability of polymerization.
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