Improved oxidation of refractory organics in concentrated leachate by a Fe²⁺-enhanced O₃/H₂O₂ process

Concentrated leachate from membrane processes, which contains a mass of refractory organics and salt, has become a new problem for wastewater engineers. In this study, removal of organic contaminants in concentrated landfill leachate was investigated by applying the ferrous ion (Fe²⁺) catalyzed O₃/H₂O₂ process. The maximum chemical oxygen demand (COD) and absorbance at 254 nm (UV₂₅₄) removal efficiencies under the optimal conditions (initial pH = 3.0, Fe²⁺ dosage = 6.500 mM, H₂O₂ dosage = 18.8 mM and O₃ dosage = 52.65 mg min^-1) were 48.82% and 63.59%, respectively. These were higher than those achieved using the Fe²⁺/O₃, O₃/H₂O₂, and O₃ processes, and biodegradability of the leachate was improved significantly. Moreover, compared with other processes, the Fe²⁺ had a stronger catalytic effect. Molecular distribution analysis and three-dimensional excitation and emission matrix analysis both indicated that the fulvic acid and humic acid in the concentrated leachate were greatly degraded. Ultraviolet-visible spectra showed that the Fe²⁺/O₃/H₂O₂ process mainly destroyed unsaturated bonds and decreased the aromatic degree of the leachate. The reaction mechanism of the Fe²⁺/O₃/H₂O₂ process mainly was attributed to three factors: (1) O₃ and H₂O₂ reacting to produce ^•OH; (2) H₂O₂ and O₃ decomposing into ^•OH through the oxidation of Fe²⁺ to Fe³⁺; and (3) coagulation by Fe (OH)₃. The ^•OH can rapidly degrade recalcitrant organics, and coagulation also increases the removal of organic matter. Therefore, the Fe²⁺/O₃/H₂O₂ process was an effective method for treating concentrated landfill leachate.