Ionic-Liquid-Modified Click-Based Porous Organic Polymers for Controlling Capture and Catalytic Conversion of CO₂

Capture and catalytic conversion of CO₂ into value-added chemicals is a promising and sustainable approach to relieve global warming and the energy crisis. Nitrogen-rich porous organic polymers (POPs) are promising materials for CO₂ capture and separation, but their application in the additive-free catalytic conversion of CO₂ into cyclic carbonates is still a challenge. Herein, a nitrogen-rich click-based POP (CPP) was developed for the cycloaddition reaction of CO₂ with epoxides in the absence of metal, solvents, and additives. The introduction of imidazolium-based ionic liquids on the CPP host backbone could modulate the porosity, CO₂ adsorption/desorption, CO₂ selectivity over N₂ , and catalytic activity in the chemical transformation. A tentative catalytic pathway was proposed to account for the superior catalytic activity of the catalytic systems, in which the incorporated ionic liquid and porous properties of CPP synergistically contributed to the catalytic reaction. This study provides a platform to understand the cooperative effects of porous properties and nucleophilic anions on the cycloaddition reaction of CO₂ with epoxides.