Understanding the Behavior of Monocationic and Dicationic Room-Temperature Ionic Liquids through Resonance
Manjari Chakraborty1, Tasnim Ahmed2, Moloy Sarkar1
1School of Chemical Sciences , National Institute of Science Education and Research , HBNI, Bhimpur-Padanpur , Jatani, Khordha, 752050 Bhubaneswar , Odisha , India.
Abstract:
The present work has been undertaken with an objective to understand the differences in the local structural organization of imidazolium-based monocationic ionic liquids (MILs) and dicationic ionic liquids (DILs) through resonance energy-transfer (RET) studies. In this study, a neat IL is used as a donor and a charged species rhodamine 6G (R6G) is used as an acceptor unit because of the fact that they satisfy the spectroscopic criteria that are needed for an RET event to take place. Additionally, R6G, being a charged species, is expected to facilitate the electrostatic interactions with the ILs which are also charged. Specifically, two imidazolium-based germinal DILs and their monocationic counterparts are used for the present investigations. Additionally, the studies are carried out in some selected MILs where the lengths of the alkyl side chains are kept unchanged for MILs and DILs. Interestingly, the present data reveal that the RET interaction is more favorable for DILs than for MILs, even though the DILs are relatively bulkier than their monocationic counterparts. More interestingly, the RET interaction is also found to be more favorable for DILs than for MILs, where the length of the alkyl group is kept fixed for MILs and DILs. The result of the present study delineates that the alkyl chain length on the cation is not the sole factor contributing to the RET outcomes for DILs and MILs but the local structure of DILs also contributes significantly to the same. The current investigation clearly indicates that DILs have a more compact local structure than that of MILs. Essentially, the current study highlights that a cost-effective, noninvasive technique such as RET is quite effective in capturing the differences in the nanostructural organization of MILs and DILs.
More Related Videos
Related Concept Videos
02:54Trends in Lattice Energy: Ion Size and Charge
02:16Resonance and Hybrid Structures
Resonance Structures and Resonance Hybrids
The Lewis structure of a nitrite anion (NO2−) may actually be drawn in two different ways, distinguished by the locations of the N–O and N=O bonds.
02:48Ionic Bonding and Electron Transfer
01:17Thermal Electrocyclic Reactions: Stereochemistry
Selection Rules: Thermal Activation
Conjugated systems containing an even number of π-electron pairs undergo a conrotatory ring closure. For example, thermal electrocyclization of (2E,4E)-2,4-hexadiene, a conjugated diene containing two π-electron pairs, gives trans-3,4-dimethylcyclobutene.
01:24IR Spectroscopy: Molecular Vibration Overview
Stretching vibrations are vibrational motions that occur along the bond line, changing the bond length or distance between two bonded atoms. They are further distinguished as symmetric or asymmetric. In symmetric stretching, the...
02:54Molecular and Ionic Solids
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...