Related Experiment Video
Updated: Jan 3, 2026
Tuning the Acidity of Pt/ CNTs Catalysts for Hydrodeoxygenation of Diphenyl Ether
Published on: August 17, 2019
Atomic structures and local electronic properties of K- and Rh-modified ceria/Pt(111) inverse model catalysts
Haoran Chen1, Wenhui Rong1, Zhichao Huang1
1BNLMS, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China.
Abstract:
Ceria has been widely applied as a support in heterogeneous catalysis due to its unique capability to store and release oxygen. As a typical inverse model catalyst, a ceria/Pt(111) system has attracted much attention due to its strong metal-oxide interaction. The structural and electronic properties of the ceria/Pt(111) system can be effectively modified by the introduction of alien K and Rh atoms. Here, the K- and Rh-modified ceria/Pt(111) inverse model catalysts have been investigated with high resolution scanning tunneling microscopy and apparent local work function measurement. The experimental results indicate that the K atoms prefer to occupy the top sites of the stoichiometric ceria, while the Rh atoms are prone to stay at the electron-rich ceria island edges. The K and Rh atoms act as an electron donor and acceptor on ceria/Pt(111), respectively. Such a study on the modification of the ceria-based catalysts should help understand strong metal-oxide interaction in heterogeneous catalysis at the atomic level.
More Related Videos
12:08Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
Published on: June 24, 2022
12:12On the Preparation and Testing of Fuel Cell Catalysts Using the Thin Film Rotating Disk Electrode Method
Published on: March 16, 2018
Related Concept Videos
02:50Catalysis
01:07Radicals: Electronic Structure and Geometry
Accordingly, the structure of a trivalent radical lies between the geometries of carbocations and carbanions. An sp2-hybridized carbocation is trigonal planar, while an sp3-hybridized carbanion is trigonal pyramidal. Here, the difference in geometry is...
02:46Crystal Field Theory - Tetrahedral and Square Planar Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
01:07Structure of Benzene: Kekulé Model
He proposed that benzene has a cyclic structure of six carbon atoms attached to one hydrogen atom each, with three alternating pi bonds.
03:26Electron Configuration of Multielectron Atoms
02:58Crystal Field Theory - Octahedral Complexes
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...