Scalable Solution Processing MoS₂ Powders with Liquid Crystalline Graphene Oxide for Flexible Freestanding Films with...

Freestanding flexible electrodes with high areal mass loading are required for the development of flexible high-performance lithium-ion batteries (LIBs). Currently they face the challenge of low mass loading due to the limited concentrations attainable in processable dispersions. Here, we report a simple low-temperature hydrothermal route to fabricate flexible layered molybdenum disulfide (MoS₂)/reduced graphene oxide (MSG) films offering high areal capacity and good lithium storage performance. This is achieved using a self-assembly process facilitated by the use of liquid crystalline graphene oxide (LCGO) and commercial MoS₂ powders at a low temperature of 70 °C. The amphiphilic properties of ultralarge LCGO nanosheets facilitates the processability of large-size MoS₂ powders, which is otherwise nondispersible in water. The resultant film with an areal mass of 8.2 mg cm^-2 delivers a high areal capacity of 5.80 mAh cm^-2 (706 mAh g^-1) at 0.1 A g^-1. This simple method can be adapted to similar nondispersible commercial battery materials for films fabrication or production of more complicated constructs via advanced fabrication technologies.