Efficient graphene-coated iron oxide (GCIO) nanoadsorbent for removal of lead and arsenic ions

ABSTRACTThe graphene-coated iron oxide (GCIO) was used for the removal of Pb²⁺ and As³⁺ ions from aqueous solution. For the characterization of GCIO, several techniques (FTIR, XRD, EDX, SEM, TEM, TGA, DSC and vibrating sample magnetometry) were used which indicated the interaction of Pb²⁺ and As³⁺ with adsorbent. In addition, the effects of adsorbate concentration, different composition of adsorbent, temperature, pH of the solution and contact time of adsorbate-adsorbent were studied. After analysis of these experiments, it was found that GCIO offered very fast removal of Pb²⁺ and As³⁺ with small amount of GCIO (0.09 g) in 100 mg/L adsorbate solution. The maximum removal of Pb²⁺ ions (up to 97.62%) was achieved when 100 mg/L standard solution of metal ion was treated with GCIO for 35 min at 45°C in weak acidic medium (5 pH). The adsorption of Pb²⁺ ions followed Freundlich model with high correlation coefficient 0.98 R². In case of As³⁺ ions, maximum removal of metal ion (up to 86.62%) was attained when 100 mg/L adsorbate solution is treated with GCIO for 25 min in slightly acidic medium (6 pH) at 25°C. The adsorption of As³⁺ ions followed D-R model with 0.98 R² value. The adsorption of both metal ions (Pb²⁺ and As³⁺) follows second-order kinetic model. The high percentage removal of metal ions with little quantity of GCIO confirmed that GCIO is an excellent, effective and economic adsorbent.