p-Pyridine BODIPY-based fluorescence probe for highly sensitive and selective detection of picric acid

A novel fluorescence probe p-PBP for PA was synthesized based on a basic N atom as the electronic donor. The probe could detect PA over TNT, CE, PETN, RDX, HMX, NB, NT, DNT, NP, DNP, and common inorganic explosive ions (K⁺, Ba²⁺, NH₄⁺, NO₃^-, ClO₃^-, and ClO₄^-), and common ions (Na⁺, Ca²⁺, and Mg²⁺) with high selectivity. The fluorescence quenching was attributed to the photo-induced electron transfer (PET) processes from the excited state of p-PBP to the ground state PA. The detection limit of probe p-PBP for PA was as low as 13.06 nmol/L, which is far lower than the concentration stipulated by the Environmental quality standards for surface water. The response time was less than 30 s. Hence, the fluorescence probe p-PBP was successfully developed to detect the concentration level of PA in real samples, which would provide a novel quantitative analysis method of PA in forensic science.