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Published on: April 25, 2020
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Martensitic organic crystals as soft actuators.
Liang Li1, Patrick Commins1, Marieh B Al-Handawi1
1New York University Abu Dhabi , Abu Dhabi , POB 129188 , United Arab Emirates .
Chemical Science
|November 27, 2019
Summary
Molecular crystals, like hexamethylbenzene, exhibit rapid martensitic phase transitions, enabling their use as efficient organic actuators. These materials offer high force-to-weight ratios and tunable mechanical properties for device applications.
Area of Science:
- Materials Science
- Crystallography
- Mechanical Engineering
Background:
- Martensitic phase transitions in molecular crystals offer potential for thermally driven organic actuators.
- Lack of standardized performance metrics hinders their adoption in device design.
- Mechanical engineering terminology is often inaccessible to chemists exploring these materials.
Purpose of the Study:
- To demonstrate the potential of organic martensites as high-performance actuators.
- To establish performance benchmarks for molecular crystal actuators.
- To bridge the gap between materials science and device engineering for organic actuators.
Main Methods:
- Investigated hexamethylbenzene as an organic martensite actuator.
- Measured uniaxial expansion rates and exerted forces during phase transitions.
- Compared performance metrics (strain, stress, force-to-weight ratio) against established actuator classes.
Main Results:
- Hexamethylbenzene crystals exhibit uniaxial expansion at 6.36(2) mm s-1, generating 10-100 mN forces.
- Achieved a force-to-weight ratio of ~104, surpassing some biological systems.
- Demonstrated high strain and stress output, competitive with advanced actuator technologies.
- Crystals showed mechanical compliance, allowing reversible bending and shaping.
Conclusions:
- Molecular crystals, exemplified by hexamethylbenzene, are viable candidates for rapid, efficient soft organic actuators.
- Standardized performance assessment facilitates their integration into actuator design.
- These materials possess significant untapped potential for diverse actuator applications.

