Related Experiment Video
Updated: Jan 3, 2026

Controlled Synthesis and Fluorescence Tracking of Highly Uniform PolyN-isopropylacrylamide Microgels
Published on: September 8, 2016
Effects of size polydispersity on random close-packed configurations of spherical particles
Patrick Mutabaruka1,2, Mahdi Taiebat1,3, Roland J-M Pellenq1
1〈MSE〉2, MIT-CNRS Joint Laboratory, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.
Abstract:
We analyze the packing properties of simulated three-dimensional polydisperse samples of spherical particles assembled by mechanical compaction with zero interparticle friction, leading to random close-packed configurations of the highest packing fraction. The particle size distributions are generated from the incomplete beta distribution with three parameters: A size span and two shape parameters that control the curvature of the distribution function. For each size distribution, the number of particles is determined by accounting for the statistical representativity of all particle size classes in terms of both the numbers and volumes of particles. Remarkably, the packing fraction increases, up to a small variability, with an effective size span, known as the coefficient of uniformity, that combines the three control parameters of the distribution. The local particle environments are characterized by the particle connectivities and anisotropies, which unveil the class of particles with four contact neighbors as the largest class with an increasing population as a function of size span, indicating the higher stability of particles trapped by four larger particles. As a result of increasing topological inhomogeneity of the packings, the force distributions get increasingly broader with increasing effective size span. Finally, we find that larger particles do not always carry stronger average stresses, in particular when the particle size distribution allows for a sufficiently large number of small particles.
Related Concept Videos
Polymers: Molecular Weight Distribution
Precipitate Formation and Particle Size Control
The obtained precipitate should be either a pure substance of known composition or easily converted to one by a simple process, such as ignition or drying. In addition, the precipitate should be insoluble and easily filterable. In general, filterability...
Pharmaceutical Alternatives: Polymorphic Form-Related and Particle Size-Related Therapeutic Nonequivalence
Factors Affecting Dissolution: Particle Size and Effective Surface Area
Pore Size Distribution
Adequate...
Van der Waals Interactions

