Curvature affects electrolyte relaxation: Studies of spherical and cylindrical electrodes

With two minimal models, I study how electrode curvature affects the response of electrolytes to applied electrostatic potentials. For flat electrodes, Bazant et al. [Phys. Rev. E 70, 021506 (2004)PLEEE81539-375510.1103/PhysRevE.70.021506] popularized the RC timescale λ_{D}L/D, with λ_{D} being the Debye length, 2L the electrode separation, and D the ionic diffusivity. For thin electric double layers near concentric spherical and coaxial cylindrical electrodes, I show here that equivalent circuit models again predict the correct ionic relaxation timescales. Importantly, these timescales explicitly depend on both electrode radii, not simply on their difference.