Efficient U(VI) adsorption on iron/carbon composites derived from the coupling of cellulose with iron oxides:...

Novel iron/carbon composites were successfully prepared via coupling of cellulose with iron oxides (e.g. α-FeOOH, Fe₂O₃ and Fe(NO₃)₃·9H₂O) at different temperatures under nitrogen atmosphere. Characterization by various techniques implied that chemical interaction between cellulose and Fe₃O₄/Fe⁰ existed in the as-prepared iron/carbon composites. The site of interaction between cellulose and iron precursors was illustrated (mainly combined with COO-). The self-reduction of Fe³⁺ to Fe²⁺ or even Fe⁰ and the interaction between carbon and Fe₃O₄/Fe⁰ in the calcination process realized the strong magnetism of the composites. Batch experiments and spectroscopic techniques indicated that the maximum adsorption capacity of MHC-7 for U(VI) (105.3 mg/g) was significantly higher than that of MGC-7 (86.0 mg/g) and MFC-7 (79.0 mg/g), indicating that Fe₂O₃ can be regarded as the remarkable iron resource for the iron/carbon composites. XPS results revealed that the oxygen-containing groups were responsible for the adsorption process of U(VI) on iron/carbon composites, and the adsorption of carbon and reduction of Fe⁰/Fe₃O₄ toward U(VI) were synergistic during the reaction process. In addition, the iron/carbon composites exhibited a good recyclability, recoverability and stability for U(VI) adsorption in the regeneration experiments. These findings demonstrated that the iron/carbon composites can be considered as valuable adsorbents in environmental cleanup and the Fe₂O₃ was a promising iron resource for the preparation of iron/carbon composites.