Related Experiment Video
Updated: Jan 3, 2026

Pretreatment of Lignocellulosic Biomass with Low-cost Ionic Liquids
Published on: August 10, 2016
Kinetic analysis of microwave-enhanced cellulose dissolution in ionic solvents
Pablo B Sánchez1, Shuntaro Tsubaki2, Agílio A H Pádua1
1Laboratoire de Chimie, École Normale Supérieure de Lyon & CNRS, 46 Allée d'Italie, 69007 Lyon, France. pablo.sanchez@ens-lyon.fr.
Abstract:
Cellulose dissolution in mixtures of the ionic liquid 1-ethyl-3-methylimidazolium acetate with dimethylsulfoxide, [C2C1Im][OAc] + DMSO, have been kinetically compared using conventional heating and microwave heating in a single-mode cavity with a semiconductor generator. Microwaves led to enhancements in the dissolution rate between 21 and 57% under different conditions of temperature and concentration of ionic liquid. Rate enhancement by microwaves prominently occurred at temperatures above 60 °C. Based on an Arrhenius plot and wide-band dielectric measurements we advance the hypothesis that the faster dissolution is caused by ionic motion induced by microwaves in the timescale of formation and breaking of hydrogen bonds between cellulose chains and acetate anions.
More Related Videos
11:26Towards Biomimicking Wood: Fabricated Free-standing Films of Nanocellulose, Lignin, and a Synthetic Polycation
Published on: June 17, 2014
09:20Microhoneycomb Monoliths Prepared by the Unidirectional Freeze-drying of Cellulose Nanofiber Based Sols: Method and Extensions
Published on: May 24, 2018
Related Concept Videos
Intermolecular Forces in Solutions
When the strengths of the intermolecular forces of attraction between solute and solvent species in a solution are no different than those present in the separated components, the solution is formed with no accompanying energy change. Such a solution is called an ideal solution. A mixture of ideal gases (or gases such as helium and argon,...
Theories of Dissolution: Diffusion Layer Model
This process starts with a thin layer, saturated with the drug, forming at the interface between the solid and liquid. The solute then diffuses from this layer into the main solution. The Noyes-Whitney equation suggests that the rate of dissolution relies on the diffusion...
Factors Affecting Dissolution: Particle Size and Effective Surface Area
Theories of Dissolution: The Danckwerts' Model and Interfacial Barrier Model
In Vitro Drug Dissolution: Alternative Methods
Aqueous Solutions and Heats of Hydration
When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process...