Energy capture from thermolytic solutions and simulated sunlight coupled with hydrogen peroxide production and...

A novel solar salinity energy nexus was developed by combining a photocatalytic fuel cell (PFC) and a reverse electrodialysis (RED). The hybrid cell (called a PRC) can effectively transfer the solar energy and salinity gradient energy (which is regenerated by low grade industrial waste heat) to electrical energy coupled with enhanced pollutant (Rhodamine B, RhB) degradation and H₂O₂ production. Energy-Environment win-win will be realized. The open circuit voltage of the PRC was the sum of those of the PFC and the RED, and the RED stack made the larger contribution to the electricity production of PRC. The bias voltage generated from the RED stack accelerated the separation of photo-induced holes and electrons on the three-dimensional TiO₂ array photoanode, which enhanced RhB degradation and H₂O₂ production. The flow rate and concentration of the working fluids (ammonium bicarbonate) and the reaction conditions in the electrode chambers had substantial effects on the PRC performance. Under the optimal condition, the peak power density and energy efficiency of PRC reached 1500 mW m^-2 and 4.21% respectively. The performance of PRC on electricity production is better than photocatalytic electrolytic cell driven by desalination(PFCD), but not good as microbial reverse electrodialysis electrolysis cell (MREC).