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Published on: February 27, 2019
Reconfigurable Chiral Plasmonics beyond Single Chiral Centers
Minh-Kha Nguyen1,2, Anton Kuzyk1
1Department of Neuroscience and Biomedical Engineering , Aalto University School of Science , P.O. Box 12200, FI-00076 Aalto , Finland.
Researchers used DNA origami to create reconfigurable chiral plasmonic stereoisomers with multiple chiral centers. This advances the development of functional chiral materials for applications in plasmonics and beyond.
Area of Science:
- Plasmonics
- DNA nanotechnology
- Chirality
Background:
- Chirality transfer into physical properties of chiral materials is crucial for plasmonics.
- DNA origami enables fabrication of complex chiral plasmonic assemblies, but mostly enantiomers.
- Multiple chiral centers offer pathways beyond simple enantiomers.
Purpose of the Study:
- To explore the implications of new findings for functional chiral plasmonic systems.
- To report on DNA origami-based assembly and characterization of reconfigurable plasmonic chiral stereoisomers.
Main Methods:
- Utilizing DNA origami techniques for assembly.
- Characterizing reconfigurable plasmonic chiral stereoisomers.
- Investigating systems with up to three chiral centers.
Main Results:
- Demonstrated DNA origami-based assembly of reconfigurable plasmonic chiral stereoisomers.
- Successfully characterized structures with multiple chiral centers.
Conclusions:
- The study provides a foundation for developing advanced functional chiral plasmonic systems.
- Highlights the potential of stereoisomers beyond enantiomers in chiral material design.
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