Sr-Doped Cubic In₂O₃/Rhombohedral In₂O₃ Homojunction Nanowires for Highly Sensitive and Selective Breath Ethanol...

In recent years, it is urgent and challenging to fabricate highly sensitive and selective gas sensors for breath analyses. In this work, Sr-doped cubic In₂O₃/rhombohedral In₂O₃ homojunction nanowires (NWs) are synthesized by one-step electrospun technology. The Sr doping alters the cubic phase of pure In₂O₃ into the rhombohedral phase, which is verified by the high-resolution transmittance electron microscopy, X-ray diffraction, and Raman spectroscopy, and is attributable to the low cohesive energy as calculated by the density functional theory (DFT). As a proof-of-concept of fatty liver biomarker sensing, ethanol sensors are fabricated using the electrospun In₂O₃ NWs. The results show that 8 wt % Sr-doped In₂O₃ shows the highest ethanol sensing performance with a high response of 21-1 ppm, a high selectivity over other interfering gases such as methanol, acetone, formaldehyde, toluene, xylene, and benzene, a high stability measured in 6 weeks, and also a high resistance to high humidity of 80%. The outstanding ethanol sensing performance is attributable to the enhanced ethanol adsorption by Sr doping as calculated by DFT, the stable rhombohedral phase and the preferred (104) facet exposure, and the formed homojunctions favoring the electron transfer. All these results show the effective structural modification of In₂O₃ by Sr doping, and also the great potency of the homojunction Sr-doped In₂O₃ NWs for highly sensitive, selective, and stable breath ethanol sensing.