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Behaviour of waste polypropylene pyrolysis char-based epoxy composite materials
Merve Sogancioglu1, Esra Yel2, Gulnare Ahmetli3
1Faculty of Engineering and Natural Sciences, Environmental Engineering Department, Konya Technical University, Konya, Turkey. msogancioglu@ktun.edu.tr.
Polypropylene plastic waste was pyrolyzed into char, then used to create epoxy composites. Composites made with char from 300°C pyrolysis showed the best mechanical and water absorption properties.
Area of Science:
- Materials Science
- Polymer Chemistry
- Waste Management
Background:
- Polypropylene (PP) plastic waste poses environmental challenges.
- Pyrolysis offers a method for converting plastic waste into valuable materials.
- Epoxy composites are widely used but can be enhanced with novel fillers.
Purpose of the Study:
- To investigate the use of polypropylene char as a filler in epoxy composites.
- To determine the effect of pyrolysis temperature on char properties and composite performance.
- To evaluate the mechanical, thermal, and water absorption characteristics of the developed composites.
Main Methods:
- Polypropylene waste was pyrolyzed at temperatures ranging from 300°C to 700°C.
- The resulting char was characterized using elemental analysis, FTIR, SEM, BET, and TGA.
- Epoxy composites were fabricated with varying char content and tested for hardness, tensile strength, elongation at break, electrical conductivity, thermal stability, and water absorption.
Main Results:
- Char derived from pyrolysis at 300°C resulted in epoxy composites with superior properties.
- Pyrolysis temperature significantly influenced the char's characteristics and its impact on composite performance.
- The epoxy composite utilizing 300°C char exhibited optimal mechanical strength, thermal stability, and water resistance.
Conclusions:
- Pyrolysis of polypropylene waste provides a viable route to producing functional fillers for epoxy composites.
- The pyrolysis temperature is a critical parameter controlling the effectiveness of the char filler.
- Epoxy composites incorporating low-temperature pyrolyzed polypropylene char demonstrate promising performance for various applications.
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