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Vibrational Energy Redistribution between CH Stretching Modes in Alkyl Chain Monolayers Revealed by Time-Resolved

Michael Lackner1, Marvin Hille1, Eckart Hasselbrink1

  • 1Fakultät für Chemie and Center for Nanointegration (CENIDE) , Universität Duisburg-Essen , D-45117 Essen , Germany.

The Journal of Physical Chemistry Letters
|December 12, 2019
PubMed
Summary

Energy rapidly transfers between CH stretching modes in fatty acid films within 2 picoseconds. Subsequent energy redistribution occurs over 85 picoseconds, with full spectral recovery in nanoseconds, indicating substrate dissipation.

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