Exploiting kinetics for assembly of multicomponent nanoparticle networks with programmable control of heterogeneity
Jessica L Davis1, Karunamuni L Silva, Stephanie L Brock
1Department of Chemistry, Wayne State University, Detroit, MI 48202, USA. sbrock@chem.wayne.edu.
Abstract:
Kinetic control of metal chalcogenide nanoparticle oxidative assembly is realized by varying the redox potential of the chalcogenide, structure (wurtzite vs. zinc blende), and ligand chain length. This knowledge is exploited to form two-component (ZnS + CdSe) hybrid aerogels with minimal heterobonding (phase-segregated) or maximal heterobonding (intimately mixed).
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