Thorium(iv) and uranium(vi) compounds of cucurbit[10]uril: from a one-dimensional nanotube to a supramolecular...

Cucurbit[10]uril {Q[10]} has the largest portal size and cavity in the series of Q[n] (n = 5-10) molecules. In contrast to its rich host-guest chemistry, its coordination chemistry is underdeveloped with only limited metal ions being investigated so far. In this work, we initiated the study of Q[10] complexes with Th(iv) and U(vi) ions in HCl solutions via a self-assembly approach. The coordination of Th(iv) ions with Q[10] led to the formation of a compound, {Th4(Cl)16(H2O)20(Q[10])}·nH2O (Q[10]-Th), with a unique nano-tubular structure, while U(vi) ions facilitated the formation of a compound, [(UO2)2(Cl)4(H2O)6]·(Q[10])2·HCl·nH2O (Q[10]-U), with a Q[10]-based supramolecular framework structure via intermolecular outer-surface and second-shell interactions. The structural and spectroscopic aspects of the two compounds together with their optical and thermal properties have been investigated. The successful preparation and characterization of the first two Q[10] compounds with Th(iv)/U(vi) ions highlighted the potential for further exploration of Q[10] coordination chemistry with actinide ions.