Removal of fluoride ion from aqueous solutions by titania-grafted β-cyclodextrin nanocomposite

TiO₂-grafted β-cyclodextrin nanocomposite was synthesized by treating the triazole modified β-cyclodextrin with the amino functionalized titanium dioxide nanoparticles, and applied for removal of fluoride ion from aqueous media by batch technique. The structural changes of nanocomposite before and after fluoride sorption were characterized using BET, BJH, AFM, and elemental mapping based on EDX analyses. The adsorption parameters including pH, adsorbent dosage, contact time, temperature, initial fluoride ion concentration, and coexisting anions have been investigated to determine the optimal adsorption conditions. The experimental data were evaluated by the Langmuir, Freundlich, and Temkin isotherms, and the pseudo-first order, pseudo-second order, and intraparticle diffusion kinetic models. Evaluation of experimental data with adsorption isotherms, Langmuire (R² = 0.9988 and Q_max = 48.78 mg g^-1), Temkin (R² = 0.9939), and Freundlich (n_F = 2.73) reveals the high adsorption efficiency of nanocomposite and suggests a monolayer chemical adsorption for fluoride ions. The adsorption experimental data fitted well with the pseudo-second order kinetic model, suggesting that a chemical sorption is involved in the rate-determining step. Thermodynamic parameters (ΔG° < 0, ΔH° > 0 and ΔS° > 0) confirmed the spontaneity, feasibility, and endothermic nature of fluoride sorption. The nanoadsorbent was regenerated in NaOH solution and reused for three adsorption-desorption cycles. The adsorption results represented the nanocomposite as a potential adsorbent for the fluoride ions removal from aqueous solutions.