Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

High serum transthyretin concentrations identify a low likelihood of advanced myocardial amyloid burden in suspected ATTR cardiomyopathy.

European journal of heart failure·2026
Same author

Formation of Gallium Monofluoride in the Coordination Sphere of Nickel.

Angewandte Chemie (International ed. in English)·2026
Same author

Zinc Halide Flux-Assisted Vitrification of Metal-Organic Frameworks Enables Chemical Diversification and Tunable Gas Sorption.

Journal of the American Chemical Society·2026
Same author

Ultra-High-Throughput Discovery of Multifunctional Polyphenolic Coatings on Droplet Microarrays.

Advanced materials (Deerfield Beach, Fla.)·2026
Same author

Differential effects of transcatheter edge-to-edge repair on forward stroke volume in atrial and ventricular secondary mitral regurgitation.

Clinical research in cardiology : official journal of the German Cardiac Society·2026
Same author

Circularly Polarized Luminescent and Melt-Processable Copper(I)-Organic Glasses Based on 2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl.

Angewandte Chemie (International ed. in English)·2026

Related Experiment Video

Updated: Jan 1, 2026

Author Spotlight: Exploring Self-Assembled MOF-Polymer Composites
06:48

Author Spotlight: Exploring Self-Assembled MOF-Polymer Composites

Published on: June 14, 2024

2.4K

Defect Creation in Surface-Mounted Metal-Organic Framework Thin Films.

Zheng Wang, Sebastian Henke1, Michael Paulus2

  • 1Anorganische Chemie, Fakultät für Chemie und Chemische Biologie , Technische Universität Dortmund , Otto-Hahn Str. 6 , 44227 Dortmund , Germany.

ACS Applied Materials & Interfaces
|December 17, 2019
PubMed
Summary
This summary is machine-generated.

Defect engineering in surface-mounted metal-organic frameworks (MOFs) was achieved using defect-generating linkers. This study introduces two novel methods for controlled defect incorporation in MOF thin films.

Keywords:
HKUST-1SURMOFUV−visdefect engineeringdefective linkersthin films

More Related Videos

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance
08:12

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance

Published on: September 5, 2018

16.5K
Electrophoretic Crystallization of Ultrathin High-performance Metal-organic Framework Membranes
07:45

Electrophoretic Crystallization of Ultrathin High-performance Metal-organic Framework Membranes

Published on: August 16, 2018

10.3K

Related Experiment Videos

Last Updated: Jan 1, 2026

Author Spotlight: Exploring Self-Assembled MOF-Polymer Composites
06:48

Author Spotlight: Exploring Self-Assembled MOF-Polymer Composites

Published on: June 14, 2024

2.4K
Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance
08:12

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance

Published on: September 5, 2018

16.5K
Electrophoretic Crystallization of Ultrathin High-performance Metal-organic Framework Membranes
07:45

Electrophoretic Crystallization of Ultrathin High-performance Metal-organic Framework Membranes

Published on: August 16, 2018

10.3K

Area of Science:

  • Materials Science
  • Nanotechnology
  • Chemistry

Background:

  • Defect engineering is crucial for tuning metal-organic framework (MOF) properties.
  • While bulk MOF defect chemistry is well-studied, defect-engineered surface-mounted MOF (SURMOF) thin films are less common.
  • Controlling defects in SURMOF thin films is essential for advanced applications.

Purpose of the Study:

  • To develop and demonstrate methods for incorporating defects into SURMOF thin films.
  • To investigate the use of defect-generating linkers for controlled defect formation.
  • To analyze the structural and chemical characteristics of defect-engineered SURMOFs.

Main Methods:

  • Utilized liquid-phase stepwise epitaxial layer-by-layer growth (LBL) for SURMOF fabrication.
  • Employed two LBL-based methods: mixing and alternating methods.
  • Incorporated defect-generating linkers (H2ip, H2OH-ip, H2pydc) to substitute the parent H3btc linker in HKUST-1 SURMOFs.

Main Results:

  • Successfully incorporated defects into SURMOF thin films using the proposed methods.
  • Confirmed crystallinity and phase purity of defected SURMOFs via XRD, IRRAS, and Raman spectroscopy.
  • Characterized linker incorporation and defect types using UV-Vis, TOF-SIMS, methanol adsorption, SEM, and 1H NMR.

Conclusions:

  • The mixing and alternating LBL methods enable controlled defect formation in MOF thin films.
  • This work provides a foundation for defect engineering in SURMOFs.
  • Defect engineering in SURMOFs opens new possibilities for tailored material properties.