N-Doped Modified Graphene/Fe₂O₃ Nanocomposites as High-Performance Anode Material for Sodium Ion Storage

Sodium-ion storage devices have received widespread attention because of their abundant sodium resources, low cost and high energy density, which verges on lithium-ion storage devices. Electrochemical redox reactions of metal oxides offer a new approach to construct high-capacity anodes for sodium-ion storage devices. However, the poor rate performance, low Coulombic efficiency, and undesirable cycle stability of the redox conversion anodes remain a huge challenge for the practical application of sodium ion energy storage devices due to sluggish kinetics and irreversible structural change of most conversion anodes during cycling. Herein, a nitrogen-doping graphene/Fe₂O₃ (N-GF-300) composite material was successfully prepared as a sodium-ion storage anode for sodium ion batteries and sodium ion supercapacitors through a water bath and an annealing process, where Fe₂O₃ nanoparticles with a homogenous size of about 30 nm were uniformly anchored on the graphene nanosheets. The nitrogen-doping graphene structure enhanced the connection between Fe₂O₃ nanoparticles with graphene nanosheets to improve electrical conductivity and buffer the volume change of the material for high capacity and stable cycle performance. The N-GF-300 anode material delivered a high reversible discharge capacity of 638 mAh g^-1 at a current density of 0.1 A g^-1 and retained 428.3 mAh g^-1 at 0.5 A g^-1 after 100 cycles, indicating a strong cyclability of the SIBs. The asymmetrical N-GF-300//graphene SIC exhibited a high energy density and power density with 58 Wh kg^-1 at 1365 W kg^-1 in organic solution. The experimental results from this work clearly illustrate that the nitrogen-doping graphene/Fe₂O₃ composite material N-GF-300 is a potential feasibility for sodium-ion storage devices, which further reveals that the nitrogen doping approach is an effective technique for modifying carbon matrix composites for high reaction kinetics during cycles in sodium-ion storage devices and even other electrochemical storage devices.