Quantum dot embedded N-doped functionalized multiwall carbon nanotubes boost the short-circuit current of Ru(ii)...

Here, we report zinc sulfide quantum dots, ZnS(QDs), moored on N-doped functionalized multiwall carbon nanotubes (MWCNTs) wrapped with reduced graphene oxide (rGO). The MWCNTs have a tangled network, a particular surface area, and a distinctive hollow structure that may be suitable for use as a counter electrode (CE) material. A ZnS@N.f-MWCNTs@rGO composite as the CE on a fluorine-doped tin oxide substrate in a dye-sensitized solar cell (DSSC) was fabricated using a doctor blade technique. The electrochemical performance showed that at the electrolyte/CE interface, the ZnS(QDs) and N-doped functionalized MWCNTs wrapped with rGO (ZnS@N.f-MWCNTs@rGO) electrode has a lower transfer charge resistance (R_ct) and a greater catalytic capacity than naked ZnS(QDs). A power conversion efficiency (PCE) of 9.4% was attained for this DSSC gadget, which is higher than that of a DSSC gadget utilizing ZnS(QDs), ZnS@N.f-MWCNTs, ZnS@rGO and Pt. Also, the DSSC device using ZnS@N.f-MWCNTs@rGO had a fill factor (FF) that was better than the other counter electrodes. The cyclic voltammetry and electrochemical impedance spectra (EIS) electron transfer measurements showed that ZnS@N.f-MWCNTs@rGO films can provide fast electron transfer from the electrolyte to the CE and great electrocatalytic activity to reduce triiodide to a CE based on ZnS@N.f-MWCNTs@rGO in the DSSC.