Related Experiment Video
Updated: Jan 1, 2026

Measuring Carbon-based Contaminant Mineralization Using Combined CO2 Flux and Radiocarbon Analyses
Published on: October 21, 2016
Modeling Trihalomethane Increases Associated with Source Water Bromide Contributed by Coal-Fired Power Plants in the
Abstract:
Increases in source water bromide concentrations are challenging for drinking water utilities since bromide contributes to the formation of disinfection byproducts (DBPs) that have negative human-health effects. The present work evaluates the role of coal-fired power plant wet flue gas desulfurization (FGD)-associated bromide loads on in-stream bromide concentrations in the Monongahela River Basin in the water year (WY) 1998 (during a nationwide study) and over a five-year period from WYs 2013 through 2017. Under mean flow conditions in the lower Monongahela River for the WYs of interest, the median-estimated wet FGD bromide discharges are modeled to represent a significant fraction (27-57%) of observed bromide concentrations with the range representing the change in load conditions across WYs. Seasonal effects are predicted due to changes in the dilution capacity of the river with elevated concentrations under lower flows in the third and fourth quarters (July through December). The effect of these bromide concentration contributions, which range from 6.8 to 23 μg/L under median load estimates and median flow conditions, on trihalomethane (THM) formation and associated risk were assessed. A simple model was applied to demonstrate an analytical approach for evaluating the power plant total THM (TTHM) and risk contributions. Utilizing this model, the power plant TTHM contribution was estimated to range from 7.6 to 27 μg/L with a median risk contribution of 0.0014.
Related Concept Videos
Halogenation of Alkenes
Consider the bromination of cyclopentene. Molecular bromine is polarized in the proximity of the π electrons of cyclopentene. An electrophilic bromine atom adds across the double bond, forming a cyclic bromonium ion intermediate.
Formation of Halohydrin from Alkenes
Electrophilic Aromatic Substitution: Chlorination and Bromination of Benzene
Radical Substitution: Halogenation of Alkanes and Alkyl Substituents
In the initiation step of the reaction, the chlorine molecule undergoes homolytic cleavage in the presence of light or heat, forming two highly reactive chlorine radicals. Propagation occurs in two...
Radical Substitution: Hydrogenolysis of Alkyl Halides with Tributyltin Hydride
The bonds formed in this reaction are stronger than the bonds broken, making it energetically favorable. The reaction follows a radical chain mechanism similar to radical halogenation reactions,...
Electrophilic Addition to Alkynes: Hydrohalogenation

