Accurate Control of VS₂ Nanosheets for Coexisting High Photoluminescence and Photothermal Conversion Efficiency

In two-dimensional (2D) amorphous nanosheets, the electron-phonon coupling triggered by localization of the electronic state as well as multiple-scattering feature make it exhibit excellent performance in optical science. VS₂ nanosheets, especially single-layer nanosheets with controllable electronic structure and intrinsic optical properties, have rarely been reported owing to the limited preparation methods. Now, a controllable and feasible switching method is used to fabricate 2D amorphous VS₂ and partial crystallized 2D VO₂ (D) nanosheets by altering the pressure and temperature of supercritical CO₂ precisely. Thanks to the strong carrier localization and the quantum confinement, the unique 2D amorphous structures exhibit full band absorption, strong photoluminescence, and outstanding photothermal conversion efficiency.