Size-Controlled Patterning of Single-Crystalline Perovskite Arrays toward a Tunable High-Performance Microlaser

Single-crystalline halide perovskites with regular morphology are of great significance for laser applications because they can be used to fabricate a natural whispering-gallery-mode resonator. Although enormous efforts have been put to synthesize single-crystalline perovskites, controlling the lateral size and thickness of the crystal, particularly at the nanoscale, is still challenging. Here, we report a facile and high-throughput strategy to selectively one-step create micro/nanoscale size-controlled all-inorganic perovskite single-crystal arrays by surface-tension-confined evaporative assembly. Our method can be used to easily tune the single crystal size and selectively position the single crystal, with versatility in fabricating perovskite single-crystal arrays in a wafer scale. When the patterned size increases from 2 to 25 μm, the width of the CsPbClBr₂ perovskite microplates increased from 150 nm to 4.2 μm. Fixing the width of the microplates at 1.6 μm, with the increase of the sliding speed from 50 to 250 mm/min, we could significantly control the thicknesses from 270 to 430 nm. Additionally, our present study provides a characterization of lasers based on different three-dimensional structures, confirming their width-dependent lasing mode and thickness-dependent lasing threshold characteristic, which is beneficial for the tunability of a high-performance microlaser.