[Determination of Heavy Metal Geochemical Baseline Values and Its Accumulation in Soils of the Luanhe River Basin,...

A total of 351 surface soil samples (0-20 cm) were collected from the Luanhe River Basin in Chengde City (a typical area of concentrated mineral resources) and analyzed for 12 heavy metals (Cu, Ni, Cd, Cr, Pb, Zn, Hg, V, Ti, Mn, As, and Co). The geochemical baseline values of the heavy metals were determined using the reference element method and the cumulative frequency curve method. Furthermore, the spatial structure and distribution characteristics of the heavy metals were assessed based on PCA and geostatistical analysis. The accumulation of heavy metal pollution in different types of soil and in association with different land use patterns was also evaluated using a geological accumulative index. The results showed that the geochemical baseline values of V, Ti, Cd, Pb, Mn, and Co in the surface soils of the Luanhe River Basin were higher than their background values for Hebei Province. In contrast, the geochemical baseline values of As, Zn, Cr, Cu, Ni, and Hg were lower than their background values. The average accumulation index of the surface soils followed the order of Cd > Pb > Cu > Ti > Mn > Zn > Cr > Ni > Co > V > Hg > As. More than 80% of the soil samples were categorized as having no accumulation or moderate accumulation of Pb, Ti, V, As, and Co, while over 70% of the soil samples were categorized as having no accumulation or moderate accumulation of Hg, Mn, Ni, Cu, As, Cd, and Cr. With respect to different soil types, the average accumulation index of heavy metals followed the order of fluvo-aquic soil>cinnamon soil>brown soil. With respect to land use types, the accumulation index of heavy metals followed the order of industrial and mining land > shrub forest land > agricultural land > woodland and grassland. The accumulation of Pb and Cd in the surface soils of agricultural land was relatively high in comparison to the other elements, with 27.69% and 25.38% of the samples being above the moderate accumulation level, respectively. The iron group elements Ti, V, Co, Ni, and Cr are likely to derive from naturally high geological background sources, while the spatial patterns of Cd, Pb, Zn, Mn, Cu, and As were associated with the combination of parent material and anthropogenic inputs. The accumulation of Hg was mainly influenced by human activities.