Synthesis and characterization of polyethylene glycol-phenol-formaldehyde based polyurethane composite

A series of phenol-formaldehyde-polyethylene glycol polyether polyols (PF-PEGs) were synthesized through the condensation polymerization and etherification of phenol, formaldehyde, and poly(ethylene glycol) (PEG) under alkaline conditions and subsequently reacted with 1,6-hexamethylene diisocyanate to obtain polyurethane (PU) films using acetone as solvents. The influence of phenol and formaldehyde to PEG mass ratio ((P + F)/PEG) on the hydroxyl number of PF-PEGs and mechanical properties, thermal stabilities, crystallization behaviors, as well as microstructure of polyurethane composite films were studied using chemical analysis, mechanical tests, thermogravimetric analyses (TGA), dynamic mechanical analyses (DMA), X-ray diffraction (XRD), scanning and transmission electron microscopies (SEM and TEM), respectively. Results demonstrated that PF-PEGs with (P + F)/PEG of 50/50 had the highest hydroxyl number of 323 mg K(OH)/g. The incorporation of phenol and formaldehyde into PEG improved the mechanical properties of polyurethane films, glass transition temperature (T_g), and thermal properties but resulted in the brittleness characteristic of the composite films and low crystallization properties. Moreover, the synthesis mechanism of PF-PEGs polyurethane composite films was revealed, which would provide a theoretical base for the preparation of the rigid polyurethane foams based on phenolic resins.