Related Experiment Video
Updated: Jan 1, 2026

Heterogeneous Removal of Water-Soluble Ruthenium Olefin Metathesis Catalyst from Aqueous Media Via Host-Guest Interaction
Published on: August 23, 2018
Hydrogenative Depolymerization of End-of-Life Poly-(Bisphenol A Carbonate) Catalyzed by a Ruthenium-MACHO-Complex
Tim-Oliver Kindler1, Christoph Alberti1, Jannis Sundermeier1
1Universität Hamburg Institut für Anorganische und Angewandte Chemie Martin-Luther-King-Platz 6 D-20146 Hamburg Germany.
Abstract:
The valorization of waste to valuable chemicals can contribute to a more resource-efficient and circular chemistry. In this regard, the selective degradation of end-of-life polymers/plastics to produce useful chemical building blocks can be a promising target. We have investigated the hydrogenative depolymerization of end-of-life poly(bisphenol A carbonate). Applying catalytic amounts of the commercial available Ruthenium-MACHO-BH complex the end-of-life polycarbonate was converted to bisphenol A and methanol. Importantly, bisphenol A can be reprocessed for the manufacture of new poly-(bisphenol A carbonate) and methanol can be utilized as energy storage material.
Related Concept Videos
Olefin Metathesis Polymerization: Ring-Opening Metathesis Polymerization (ROMP)
Olefin Metathesis Polymerization: Overview
Ruthenium-based Grubbs catalyst is the most commonly used catalyst for olefin metathesis polymerization. Grubbs catalyst consists of a...
Radical Substitution: Hydrogenolysis of Alkyl Halides with Tributyltin Hydride
The bonds formed in this reaction are stronger than the bonds broken, making it energetically favorable. The reaction follows a radical chain mechanism similar to radical halogenation reactions,...
Reduction of Alkenes: Asymmetric Catalytic Hydrogenation
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
Hydroboration-Oxidation of Alkenes
Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation
Like alkenes, alkynes can be reduced to alkanes in the presence of transition metal catalysts such as Pt, Pd, or Ni. The reaction involves two sequential syn additions of hydrogen via a cis-alkene intermediate.

