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Synthesis of Cyclic Polymers and Characterization of Their Diffusive Motion in the Melt State at the Single Molecule Level
Published on: September 26, 2016
Generalized diffusion of quantum Brownian motion
1Departamento de Química. Universidad de Los Andes, Mérida 5101, Venezuela.
Abstract:
This article discusses the numerical result predicted by the quantum Langevin equation of the generalized diffusion function of a Brownian particle immersed in an Ohmic quantum bath of harmonic oscillators. The time dependence of the standard deviation of the reduced Wigner function of the system, obtained by integrating the whole function in the momentum space, is determined as well. The complexity of the equations leads to resort to a much simpler calculation based in the position correlation function. They are done for the three possible regimes of the system, namely, periodic, aperiodic, and overdamped. It is found in the periodic case that the generalized diffusion is a discontinuous function exhibiting negative values during short time periods of time. This counterintuitive result, found theoretically in other systems and waiting for its experimental confirmation, can be perfectly explained in the framework of the quantum Langevin equation. Its oscillatory behavior is primordially due to the response to the external field while its quantum origin contributes only in its magnitude. The results are compared to those of the continuum limit which exhibits similar behavior.
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