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Precharging Photon Upconversion: Interfacial Interactions in Solution-Processed Perovskite Upconversion Devices.

Sarah Wieghold1, Lea Nienhaus1

  • 1Department of Chemistry and Biochemistry , Florida State University , Tallahassee , Florida 32306 , United States.

The Journal of Physical Chemistry Letters
|January 3, 2020
PubMed
Summary
This summary is machine-generated.

Photon upconversion in perovskite/rubrene systems is better understood by examining the interface. Noncovalent interactions and band bending explain initial efficiency and subsequent steady-state upconversion.

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Area of Science:

  • Materials Science
  • Photophysics
  • Organic Electronics

Background:

  • Perovskite-sensitized photon upconversion (PS-UC) via triplet-triplet annihilation (TTA) in rubrene is a promising technology.
  • Unanswered questions remain regarding the interfacial mechanisms and processes governing PS-UC efficiency.

Purpose of the Study:

  • To investigate the perovskite/rubrene interface in detail.
  • To elucidate the underlying mechanism of photon upconversion and observed phenomena like reversible photobleaching.

Main Methods:

  • Detailed investigation of the perovskite/rubrene interface.
  • Analysis of noncovalent interactions and band bending effects.
  • Study of charge transfer dynamics upon illumination.

Main Results:

  • Noncovalent interactions between perovskite and rubrene passivate surface traps.
  • Band bending creates a space charge region, precharging rubrene with holes.
  • Initial illumination facilitates rapid electron transfer and efficient TTA upconversion.

Conclusions:

  • The perovskite/rubrene interface plays a critical role in TTA upconversion efficiency.
  • Surface trap passivation and hole precharging are key to initial high efficiency.
  • A dynamic equilibrium explains the transition to steady-state upconversion efficiency.