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Updated: Dec 31, 2025

Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
Published on: December 6, 2021
A new cobalt metal-organic framework as a substrate for Pd nanoparticles applied in high-efficiency nitro phenol
Zhida Liu1, Liangmin Ning, Kaiyuan Wang
1College of Chemistry, Key Laboratory of Advanced Energy Materials Chemistry(MOE), Tianjin Key Laboratory of Metal and Molecule Based Material Chemistry, Collaborative Innovation Centre of Chemical Science and Engineering, Nankai University, Tianjin, 300071, China. liuxin64@nankai.edu.cn guwen68@nankai.edu.cn.
Abstract:
In recent years, attributed to the excellent catalytic performance of precious metal materials, metal nanoparticles@MOF catalyst has been a popular research direction. Herein, we have synthesized a new 3D cobalt metal-organic framework [Co(TATAB)(344-pytpy)·DMF]n(H3TATAB = 4,4',4″-s-triazine-1,3,5-triyltri-p-aminobenzoic acid; 344-pytpy = 4'-(3-pyridyl)-4,2':6',4″-terpyridine)(1)(P1) by solvothermal method. Its crystal structure was determined with single-crystal X-ray diffraction (SC-XRD) techniques. The final composite Pd-NPs@1 catalyst was synthesized by a reduction method. The catalyst showed high catalytic performance and high recycling stability for nitrophenol degradation and cinnamaldehyde hydrogenation reaction.

