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Polymer Classification: Crystallinity01:21

Polymer Classification: Crystallinity

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Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
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Related Experiment Video

Updated: Dec 31, 2025

Microfluidic Preparation of Liquid Crystalline Elastomer Actuators
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Microfluidic Preparation of Liquid Crystalline Elastomer Actuators

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Liquid-Crystalline Soft Actuators with Switchable Thermal Reprogrammability.

Yahe Wu1, Yang Yang1, Xiaojie Qian1

  • 1The Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology, Department of Chemistry, Tsinghua University, Beijing, 100084, China.

Angewandte Chemie (International Ed. in English)
|January 7, 2020
PubMed
Summary
This summary is machine-generated.

Researchers developed a strategy to switch thermal reprogrammability on and off in liquid-crystalline elastomer (LCE) actuators. This allows for on-demand 3D shape changes while maintaining high-temperature actuation stability for advanced soft robots.

Keywords:
dynamic siloxane exchangeelastomersliquid crystalssoft actuatorsswitchable thermal reprogrammability

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Area of Science:

  • Materials Science
  • Polymer Chemistry
  • Robotics

Background:

  • Soft actuators are crucial for next-generation robotics, but thermal reprogrammability often compromises actuation performance.
  • A key challenge is balancing thermal adaptability with robust mechanical stability in soft actuator design.

Purpose of the Study:

  • To develop a novel strategy for liquid-crystalline elastomer (LCE) actuators that enables switchable thermal reprogrammability.
  • To overcome the trade-off between shape-memory capabilities and high-temperature actuation stability.

Main Methods:

  • Inducing a latent siloxane exchange reaction via post-synthesis swelling in LCEs to enable reprogramming (switching 'on').
  • Utilizing thermal treatment to deactivate the dynamic network (switching 'off'), ensuring actuation stability at elevated temperatures (up to 180°C).
  • Employing selective patterning (e.g., black ink) to control reprogrammability in specific regions of the LCE actuator.

Main Results:

  • Demonstrated the ability to repeatedly switch thermal reprogrammability on and off in LCE actuators.
  • Achieved stable actuation performance at high temperatures (180°C) by switching off the dynamic network.
  • Successfully integrated multiple, distinct actuation modes within a single monolithic actuator through selective reprogramming control.

Conclusions:

  • The developed strategy effectively resolves the conflict between thermal reprogrammability and actuation stability in LCE actuators.
  • This approach allows for the creation of robust, thermally adaptable soft actuators with on-demand 3D shape-forming capabilities.
  • The ability to integrate diverse actuation modes opens possibilities for more sophisticated and complex tasks in soft robotics.