Imparting Functionality to the Hydrogel by Magnetic-Field-Induced Nano-assembly and Macro-response

Hydrogels are composed of 3D hydrophilic networks with an abundance of water; they are analogous to biological soft tissues. Their unique physico-chemical properties endow hydrogels with great potential in many fields, including tissue engineering and flexible sensing. However, inadequate functionality, such as lack of rapid responsiveness, severely limits practical applications in many areas. Therefore, imparting functionality to the hydrogel is a hot research topic. The magnetic field, as an important physical field, provides a new strategy with a variety of advantages. Magnetic-field-induced ordered nano-assembly brought anisotropic properties and novel performance. Furthermore, the magnetic responsiveness of hydrogels with magnetic nanoparticles can lead to the generation of functionality under magnetic fields. Thus, we aim to systematically describe the significant effect of magnetic fields on the functionality of the hydrogel. In this review, magnetic-field-induced assembly of nanomaterials with different dimensions and resulting functional performance are introduced. The functionalities of hydrogels based on magnetic-field-induced macroscopic responses are also summarized. We believe this review will motivate more exploration of the application of magnetic fields to develop functional hydrogel materials.