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Why do thioureas and squaramides slow down the Ireland-Claisen rearrangement?

Dominika Krištofíková1, Juraj Filo2, Mária Mečiarová1

  • 1Department of Organic Chemistry, Faculty of Natural Sciences, Comenius University in Bratislava, Mlynská dolina, Ilkovičova 6, 84215 Bratislava, Slovakia.

Beilstein Journal of Organic Chemistry
|January 11, 2020
PubMed

Keywords:
DFT calculationsH-bonding catalystsIreland–Claisen rearrangementgreen solventssilyl ketene acetals

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