In situ formation, structural, mechanical and in vitro analysis of ZrO₂/ZnFe₂O₄ composite with assorted composition...

The investigation underline the in situ formation of ZrO₂/ZnFe₂O₄ composites and the resultant structural, morphological, mechanical and magnetic properties. The characterization results ensured the crystallization of tetragonal ZrO₂ (t-ZrO₂) and ZnFe₂O₄ phases at 900 °C. Depending on Zn²⁺/Fe³⁺ content, the composite system revealed a gradual increment in the phase yield of ZnFe₂O₄. The significance of monoclinic ZrO₂ (m-ZrO₂) is also evident in all the systems at 900 °C; however, the incremental heat treatment to 1300 °C indicated its corresponding loss, thus indicating the reverse m- → t-ZrO₂ transition. The crystallization of ZnFe₂O₄ as a secondary phase in the t-ZrO₂ matrix is also affirmed from the morphological analysis. Mechanical studies accomplished good uniformity in all the investigated compositions despite the variation in the phase content of ZnFe₂O₄ in composite system. All the t-ZrO₂/ZnFe₂O₄ composites ensured strong ferrimagnetic features and moreover better biocompatibility and non-toxicity characteristics were displayed from in vitro tests.