Binary mineral sulfides sorbent with wide temperature range for rapid elemental mercury uptake from coal combustion...

Developing efficient sorbents with rapid kinetics is the main challenge encountered for Hg⁰ capture from coal combustion flue gas in a sorbent injection scenario. Binary mineral sulfide-based materials combining copper sulfide (CuS) and zinc sulfide (ZnS) to exert their capabilities for Hg⁰ capture at the low- and high-temperature was for the first time reported for Hg⁰ removal to realize a wide temperature range sorbents. When the molar ratio between CuS and ZnS was 10%, the as-synthesized 10Cu-Zn nanocomposite exhibited excellent Hg⁰ uptake rate at 150°C that could degrade 40 μg/m³ of Hg⁰ to undetectable level at the end of a 60-s experiment with the dosage of only 1 mg. This Hg⁰ uptake rate is folds higher compared to that when bare CuS or ZnS was adopted alone at this specific temperature. The typical flue gas atmospheres had negligible effect on Hg⁰ removal over 10Cu-Zn in a short contact time, which further suggests that the binary sorbents were proper to be injected before the electrostatic precipitator system. Moreover, it is found that, by adjusting the ratio between CuS and ZnS, it is potential to develop binary sorbent suiting any temperature conditions that may achieve an exceedingly high Hg⁰ capture performance. Thus, this work not only justified the candidature of 10Cu-Zn as a promising alternative to traditional activated carbon for Hg⁰ capture from coal combustion flue gas but also guided the future development of multi-component mineral sulfide-based sorbents for Hg⁰ pollution remediation from various industrial flue gases.