Electrostatically controlled plasmonic effects of gold nanoparticles with indigo-carmine functionation for rapid and...

A colorimetric sensor is fabricated for effective on-site monitoring of Cu²⁺ ions content based on the distance-dependent optical properties of gold nanoparticles-polyvinyl alcohol-citrate (Au-NPs-PVA-Cy) which plasmonic effect electrostatically was controlled by PVA-Cy stabilizing indigo-carmine (IC) functionalizing. The surface-modified gold nanoparticles were extremely stable with a strong affinity toward Cu²⁺ ions. Citrate ion was employed as a cross-linking agent for pairs of Au-NPs-PVA-Cy and IC for stabilizing coordination between Cu²⁺ ion and IC. The active materials were characterized by UV-Vis, SEM, DLS, XRD, FT-IR, and EDS analyses. The sensor response toward Cu²⁺ ion was found to be linear in the range of 0.0974 to 3.27 μM with the limit of detection and quantification values of 0.021 and 0.07 μM, respectively. The sensor represents good sensitivity and stability, promisingly suggesting this device for the accurate and repeatable determination of Cu²⁺ in real water samples. The effect of different foreign ions on the selectivity of the sensor was checked. The sensor has a long shelf life in comparison to other similar colorimetric sensors. Also, it shows a repeatable response with RSD% of 2.02%. Thus, the sensing of Cu²⁺ ions based on the electrostatically control plasmonic of Au-NPs-PVA-Cy was developed with proper signaling based on the color change from dark blue to light blue as readily seen by the naked eye. Furthermore, the efficient environmental applicability of this simple and rapid determination of the Cu²⁺ sensor is proved.