N, Ru Codoped Pellet Drum Bundle-Like Sb₂S₃: An Efficient Hydrogen Evolution Reaction and Hydrogen Oxidation Reaction...

Though investigations have been made on several metal chalcogenides in hydrogen evolution reactions (HERs) and hydrogen oxidation reactions (HORs), antimony sulfide (Sb₂S₃) has not generated much attention. In this direction, the present work reports on the synthesis of N, Ru codoped pellet drum bundle-like antimony sulfide (Sb₂S₃) via a simple reflux method. Subsequent HER and HOR electrocatalytic investigations in 1 M KOH revealed their suitability as an efficient and inexpensive alternative to platinum, as is evident from the overpotential (72 mV at a current density of 10 mA cm^-2), Tafel slope (193 mV/decade), exchange current density (1.42 mA/cm²), and breakdown potential at ∼0.6 V vs RHE, respectively. Such remarkable HER and HOR performance of N, Ru codoped Sb₂S₃ could be ascribed to the presence of relatively larger active sites compared to Sb₂S₃ and N-doped Sb₂S₃ individually due to synergistic effects arising from N and Ru dopants. Further, N, Ru codoped Sb₂S₃ demonstrated high intrinsic catalytic activity as indicated by its turnover frequency (2.03 s^-1) and current loss, corresponding to 35% after 10 h of continuous amperometric i-t operation. Alternatively, such excellent catalytic performance of N, Ru codoped Sb₂S₃ arises due to geometric lattice defects with surface oxygen vacancy, and the availability of abundant edges and its pellet drum-like morphology also cannot be overruled.