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Updated: Dec 30, 2025

Developing Photosensitizer-Cobaloxime Hybrids for Solar-Driven H2 Production in Aqueous Aerobic Conditions
Published on: October 5, 2019
Single-chromophore single-molecule photocatalyst for the production of dihydrogen using low-energy light
T J Whittemore1, C Xue1, J Huang1
1The Ohio State University, Columbus, OH, USA.
Abstract:
Single-chromophore single-molecule photocatalysts for the conversion and storage of solar energy into chemical bonds are rare, inefficient and do not use significant portions of the visible spectrum. Here we show a new, air-stable bimetallic scaffold that acts as a single-chromophore photocatalyst for hydrogen-gas generation and operates with irradiation wavelengths that span the ultraviolet to the red/near-infrared. Irradiation in acidic solutions that contain an electron donor results in the catalytic production of hydrogen with 170 ± 5 turnovers in 24 hours and an initial rate of 28 turnovers per hour. The catalysis proceeds through two stepwise excited-state redox events-atypical of the currently known homogeneous photocatalysis-and features the storage of multiple redox equivalents on a dirhodium catalyst enabled by low-energy light.
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