Multifunctional magnetic MgMn-oxide composite for efficient purification of Cd²⁺ and paracetamol pollution:...

A multifunctional magnetic composite (0.3Ma-MgMnLDO-a) with the function of Cd²⁺ adsorption and paracetamol (PAM) degradation was successfully fabricated. Surface morphology showed that Fe₃O₄ agglomeration was overcome on composite. The composite had high specific surface area of 105.32 m² g^-1 and saturation magnetization of 40 emu∙g^-1. 0.3Ma-MgMnLDO-a could reach Cd²⁺ adsorption equilibrium within 5 min with 99 % removal rate. The maximum adsorption capacity was 3.76 mmol·g^-1 (422.62 mg g^-1), which apparently higher than that of Fe₃O₄-a and MgMnLDO-a, indicating that the Fe/Mn synergism results in excellent ability for Cd²⁺ adsorption. Moreover, the composite could efficiently activate peroxymonosulfate (PMS) to rapid degrade PAM with the highest first-order rate constants (k_obs = 0.116 min^-1) and total organic carbon (TOC) removal rate (67.7 %), which also due to the contribution of Fe/Mn synergism in PMS activation. The cycling of Mn^III/Mn^IV and Fe^II/Fe^III played an important role in activating PMS to generateO₂^-•, ¹O₂ and OH for degradation. The composite exhibited both stable adsorption and catalytic performance on wide pH (3-9) and five reuse cycles. Notably, there was mutual promotion between Cd²⁺ and PAM adsorption, while the coexistence of Cd²⁺ had slight inhibition on PAM degradation. Overall, the magnetic composite had promising application for purifying heavy metals and pharmaceuticals.