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Updated: Dec 30, 2025

An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids
Published on: December 4, 2017
Density dependence of the dynamical processes governing the velocity autocorrelation function of a quantum fluid
Eleonora Guarini1, Martin Neumann2, Stefano Bellissima3
1Dipartimento di Fisica e Astronomia, Università degli Studi di Firenze, via G. Sansone 1, I-50019 Sesto Fiorentino, Italy.
Abstract:
We present an exponential mode analysis of the dynamical processes determining the time behavior of the Kubo velocity autocorrelation function (KVAF) of fluid para-H_{2}, as obtained by ring polymer molecular dynamics simulations at various fluid densities. The mechanisms contributing to the decay of the KVAF are thoroughly characterized at a slightly supercritical temperature, in a density interval ranging from the critical point to the fluid-solid transition. We show that the quantum nature of the system does not influence the specific phenomena and decay channels through which a loss in velocity correlation takes place, since these are the same as found in classical fluids. Similarly, a dynamical crossover is observed with increasing density, signaling the onset of a transverse-like dynamics like in classical systems. We also investigate the effect of density on the processes contributing to the most relevant property of a quantum fluid, namely, the large values of the total and zero-point kinetic energy arising through the Heisenberg uncertainty principle.
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