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Updated: Dec 30, 2025
05:20
Characterization of Thermal Transport in One-dimensional Solid Materials
Published on: January 26, 2014
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Specific Heat and Transport Functions ofWater.
Francesco Mallamace1,2, Carmelo Corsaro3, Domenico Mallamace3
1Department of Nuclear Science and Engineering, Massachusetts Institute of Technology,Cambridge, MA 02139, USA.
International Journal of Molecular Sciences
|January 23, 2020
Summary
Water
Area of Science:
- Physical Chemistry
- Thermodynamics
- Materials Science
Background:
- Water's unique hydrogen bonding properties are temperature-dependent.
- Structural and dynamic changes in water at low temperatures are not fully understood.
- The relationship between water's thermodynamic and dynamic properties requires further investigation.
Purpose of the Study:
- To investigate the connection between the thermodynamic and dynamic characteristics of liquid water.
- To compare the thermal behavior of water's specific heat with its configurational entropy contribution.
- To analyze water's properties under varying confinement conditions.
Main Methods:
- Experimental measurement of isobaric specific heat of water under confinement.
- Theoretical evaluation of water's thermal behavior.
- Application of the Adam-Gibbs approach to determine configurational entropy from self-diffusion coefficients.
Main Results:
- A maximum in the specific heat of water was observed around 225 K.
- Configurational contributions to entropy were found to be dominant at low temperatures.
- Strong correlation identified between water's thermodynamic and dynamic properties.
Conclusions:
- Thermodynamic and dynamic properties of water are intrinsically linked.
- Low-temperature behavior of water is significantly influenced by its molecular rearrangements.
- Confinement conditions play a crucial role in water's thermal and dynamic characteristics.
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