[Adsorption of Airbone Organophosphorus Flame Retardants on Polished Rice Stored in a House]

In order to clarify the actual situation of indoor pollution to polished rice with organophosphorus flame retardants (PFRs) which are ubiquitous in the indoor environment, the pollution of PFRs to polished rice stored in a house for a week was investigated. The survey covered 64 ordinary families in the Osaka region. We analyzed six typical PFRs in 37 rice samples in 2015, and ten typical PFRs in 27 rice samples in 2016. Polished rice was homogenized with acetone-hexane and defatted by hexane-acetonitrile partition. Quantitative analysis for PFRs was performed by GC-FPD. The detection frequency of PFRs in the rice samples was 35/37 in 2015 and 27/27 in 2016. The highest values were 160 ng/g for TCEP, 500 ng/g for TCIPP and 430 ng/g for TBEP. The concentration ratio of each detected PFR in the polished rice samples was different in each house. In the analysis of 16 polished rice samples which were stored in the home, PFRs were detected in ten samples regardless of the storage methods. PFRs were detected from 12 out of 16 commercial brown rice samples. This result suggested that they were polluted during distribution and storage process of them.