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Are Hetero-metallapentalenes Aromatic or Not? A DFT Investigation
1State Key Laboratory of Physical Chemistry of Solid Surfaces and, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Fujian Provincial Key Laboratory of Theoretical and Computational Chemistry, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, P.R. China.
Abstract:
Aromaticity is one of the most basic concepts in organic chemistry. The planar Möbius aromatic metallapentalynes and metallapentalenes have attracted considerable attention in the past few years. However, the aromaticity of metallapentalenes containing heteroatoms (such as B, N, and O), termed as hetero-metallapentalenes, is rarely studied. Herein, the stability and aromaticity of a series of hetero-metallapentalenes are theoretically investigated. The results reveal lower aromaticity in metallaborapentalene, comparable aromaticity in metallazapentalene, and nonaromaticity in metalloxapentalene relative to that of metallapentalene. Moreover, the effect of Lewis bases on the aromaticity and stability of metallaborapentalene is discussed. These results provide useful information for experimental chemists to realize more hetero-metallapentalenes.
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