Molybdenum sulfide-based electrochemical platform for high sensitive detection of taxifolin in Chinese medicine

MoS₂ and nitrogen doped active carbon composite (MoS₂/ANC) is fabricated to detect taxifolin and exhibits superior redox current response and decreased redox potential difference. Further investigation reveals that the kinetic process of the redox reaction of taxifolin on MoS₂/ANC electrode is controlled by both adsorption and diffusion process. Under the optimum conditions, the redox peak currents linearly relate with the concentration of taxifolin in the range of 1 × 10^-9-1 × 10^-6 mol L^-1, accompanied by the low detection limit (3 × 10^-10 mol L^-1). Meanwhile, outstanding selectivity, stability and repeatability are also obtained at MoS₂/ANC electrode. At last, the proposed method is applied to quantitatively detect taxifolin in fructus polygoni orientalis and satisfactory results have been achieved.